SAFETY DATA SHEET
Conductive Silver Liquid, SEM adhesive
1. IDENTIFICATION
Product Identifiers
Product Name:
Conductive Silver Liquid, SEM adhesive
Other Names:
N/A
Product Number(s):
I004, I0041
CAS Number:
-
Recommended use of the chemical and restriction on use
Fixative used in laboratory conditions.
Company Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
Emergency Contact Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
FLAMMABLE LIQUIDS - Category 2
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/EYE IRRITATION - Category 1
REPRODUCTIVE TOXICITY (Fertility) - Category 1A
REPRODUCTIVE TOXICITY (Unborn child) - Category 1A
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE - Category 2
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/EYE IRRITATION - Category 1
REPRODUCTIVE TOXICITY (Fertility) - Category 1A
REPRODUCTIVE TOXICITY (Unborn child) - Category 1A
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE - Category 2
Label Elements
Signal Words
Danger
Hazard Statement(s)
H315: Causes skin irritation.
H225: Highly flammable liquid and vapour
H318: Causes serious eye damage
H410: Very toxic to aquatic life with long-lasting effects
H225: Highly flammable liquid and vapour
H318: Causes serious eye damage
H410: Very toxic to aquatic life with long-lasting effects
Precautionary Statement(s)
P264 Wash ... thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P302 IF ON SKIN: P352 Wash with plenty of water
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor.
P332 + P313 If skin irritation occurs: Get medical advice/ attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
Disposal
P501 Dispose of contents/ container to an approved waste disposal plant.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P302 IF ON SKIN: P352 Wash with plenty of water
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor.
P332 + P313 If skin irritation occurs: Get medical advice/ attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
Disposal
P501 Dispose of contents/ container to an approved waste disposal plant.
Primary route(s) of entry
Not available.
Human Health
Inhalation:
No data available
Ingestion:
No data available
Eyes:
Mixture may cause eye irritation
Skin:
Mixture may cause skin irritation. May cause argyria (a slate-gray or bluish discoloration of the skin and deep tissues due to the deposit of insoluble albuminate of silver)
Environment
Very toxic to aquatic life
Very toxic to aquatic life with long lasting effects.
Very toxic to aquatic life with long lasting effects.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Name
CAS No.
Content (w/w)
Classification
Colloidal silver
7440-22-4
>= 70 - < 90 %
Aquatic Acute 1; Aquatic Chronic 1; H400, H410 M-Factor - Aquatic Acute: 100 - Aquatic Chronic: 100
p-Menth-1-en-8-ol
10482-56-1
>= 20 - < 30 %
Skin Corr./Irrit. 2; Eye Dam./Irrit. 1; H315, H318
Toluene
108-88-3-
~13.2-26.4%
See above in Protec Super Clear
Butanone
78-93-3
~4.4-13.2%
See above in Protec Super Clear
2-methoxy-1- methylethyl acetat
108-65-6
~0-4.4%
See above in Protec Super Clear
4. FIRST AID MEASURES
Ingestion
If patient is conscious, rinse particles from mouth with water; do not swallow. DO NOT induce vomiting. Never
give anything by mouth to an unconscious person. Obtain immediate medical attention.
give anything by mouth to an unconscious person. Obtain immediate medical attention.
Inhalation
Treat as dust inhalation. Remove patient to fresh air. Obtain medical treatment for prolonged respiratory irritation or difficulty in breathing.
Skin Contact
Remove contaminated clothing and shoes. Wash affected area with soap and water to remove particles that may cling to skin.
Eye Contact
Flush with water, including under lids, with gentle stream of water for fifteen minutes. Obtain immediate medical attention.
Other Information
Doctor to treat symptomatically.
5. FIREFIGHTING MEASURES
Suitable extinguishing equipment
Recommended to use Water Foam Carbon dioxide (CO₂) Dry powder
HAZCHEM
Carbon oxides Silver/silver oxides Mixture with combustible ingredients. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire.
Prevent fire extinguishing water from contaminating surface water or the ground water system.
Prevent fire extinguishing water from contaminating surface water or the ground water system.
Special protective equipment and precautions for fire fighters
Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Avoid inhalation of vapours/aerosols or dusts.
Avoid substance contact.
Ensure adequate ventilation.
Evacuate the danger area, observe emergency procedures, consult an expert.
Avoid substance contact.
Ensure adequate ventilation.
Evacuate the danger area, observe emergency procedures, consult an expert.
Environmental precautions
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Do not let the product enter drains/waterways.
Do not let the product enter drains/waterways.
Methods and materials for containment and clean up
Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13).
Contaminated absorbent material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
Contaminated absorbent material may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
7. HANDLING AND STORAGE
Precautions for safe handling
Avoid release to the environment. Collect spillage
Take off contaminated clothing and wash it before reuse.
Take off contaminated clothing and wash it before reuse.
Conditions for safe storage
Store tightly closed. Recommended storage temperature 2 - 8 °C
Storage class (TRGS 510): 11: Combustible Solids
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Standards
Material
TWA ppm
TWA mg/m3
STEL ppm
STEL mg/m3
Colloidal silver
7440-22-4
0.1 mg/m3
-
-
Engineering controls
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Personal protective equipment
Eye and face protection
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles
Skin protection
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
Full contact Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L Splash contact Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L
Full contact Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L Splash contact Material: Nitrile rubber Minimum layer thickness: 0.11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L
Body protection
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Respiratory protection
Required when dusts/vapours/aerosols are generated.
Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
9. PHYSICAL AND CHEMICAL PROPERTIES
General information
Appearance
Grey, lustrous paste
Odour
Not available.
pH
Not determined.
Vapour Pressure
Not available.
Density
Not available.
Boiling Point
Not available.
Melting Point
Not available.
Solubility
Not available.
Specific Gravity of Density
Not determined.
Flash Point
96.1 °C
Flammable (Explosive) Limits
Not available.
Ignition Temperature
Not available.
Formula
Not available.
10. STABILITY AND REACTIVITY
Reactivity
Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical.
Chemical stability
The product is chemically stable under standard ambient conditions (room temperature)
Possibility of hazardous reactions
No data available
Conditions to avoid
Strong heating
Incompatible materials
Oxygen, Strong acids and strong bases
11. TOXICOLOGICAL INFORMATION
Acute effects
Acute toxicity Oral: No data available Symptoms: Irritations of mucous membranes in the mouth, pharynx, oesophagus and gastrointestinal tract. Symptoms: Possible symptoms:, mucosal irritations Dermal: No data available
Skin corrosion/irritation Remarks: Mixture causes skin irritation.
Serious eye damage/eye irritation
Remarks: Mixture causes serious eye damage.
Respiratory or skin sensitization No data available
Germ cell mutagenicity No data available
Carcinogenicity No data available
Reproductive toxicity No data available
Specific target organ toxicity - single exposure No data available
Specific target organ toxicity - repeated exposure No data available
Aspiration hazard No data available
Skin corrosion/irritation Remarks: Mixture causes skin irritation.
Serious eye damage/eye irritation
Remarks: Mixture causes serious eye damage.
Respiratory or skin sensitization No data available
Germ cell mutagenicity No data available
Carcinogenicity No data available
Reproductive toxicity No data available
Specific target organ toxicity - single exposure No data available
Specific target organ toxicity - repeated exposure No data available
Aspiration hazard No data available
Eye contact
May causes serious eye damage
Skin contact
Mixture may cause skin irritation.
Ingestion
No data available
Inhalation
No data available
Toxicity and irritation
LD50 Oral - Rat - male - 4,300 mg/kg
(OECD Test Guideline 401)
Remarks: (in analogy to similar compounds)
The value is given in analogy to the following substances: terpineol (p-menth-1-en-8ol) The value is given in analogy to the following substances: terpineol
Inhalation: No data available
LD50 Dermal - Rat - female - > 2,000 mg/kg
(OECD Test Guideline 402)
Skin corrosion/irritation Skin - Rabbit Result: irritating - 4 h
(OECD Test Guideline 404)
Remarks: (in analogy to similar products)
The value is given in analogy to the following substances: terpineol (p-menth-1-en-8ol)
Serious eye damage/eye irritation
Eyes - Rabbit
Result: Causes serious eye damage.
(OECD Test Guideline 405)
Respiratory or skin sensitization
Popliteal lymph node assay (PLNA) - Rat
Result: negative
(Regulation (EC) No. 440/2008, Annex, B.42 (LLNA))
Remarks: (in analogy to similar products)
The value is given in analogy to the following substances: terpineol (p-menth-1-en-8ol)
Germ cell mutagenicity
Test Type: Ames test
Test system: S. typhimurium
Result: negative
Remarks: (in analogy to similar products)
The value is given in analogy to the following substances: terpineol (p-menth-1-en-8ol)
Test Type: In vitro mammalian cell gene mutation test
Test system: mouse lymphoma cells
Result: negative
Remarks: (in analogy to similar products)
The value is given in analogy to the following substances: terpineol (p-menth-1-en-8ol)
Carcinogenicity No data available
Reproductive toxicity No data available
Specific target organ toxicity - single exposure No data available
Specific target organ toxicity - repeated exposure No data available
Aspiration hazard No data available
(OECD Test Guideline 401)
Remarks: (in analogy to similar compounds)
The value is given in analogy to the following substances: terpineol (p-menth-1-en-8ol) The value is given in analogy to the following substances: terpineol
Inhalation: No data available
LD50 Dermal - Rat - female - > 2,000 mg/kg
(OECD Test Guideline 402)
Skin corrosion/irritation Skin - Rabbit Result: irritating - 4 h
(OECD Test Guideline 404)
Remarks: (in analogy to similar products)
The value is given in analogy to the following substances: terpineol (p-menth-1-en-8ol)
Serious eye damage/eye irritation
Eyes - Rabbit
Result: Causes serious eye damage.
(OECD Test Guideline 405)
Respiratory or skin sensitization
Popliteal lymph node assay (PLNA) - Rat
Result: negative
(Regulation (EC) No. 440/2008, Annex, B.42 (LLNA))
Remarks: (in analogy to similar products)
The value is given in analogy to the following substances: terpineol (p-menth-1-en-8ol)
Germ cell mutagenicity
Test Type: Ames test
Test system: S. typhimurium
Result: negative
Remarks: (in analogy to similar products)
The value is given in analogy to the following substances: terpineol (p-menth-1-en-8ol)
Test Type: In vitro mammalian cell gene mutation test
Test system: mouse lymphoma cells
Result: negative
Remarks: (in analogy to similar products)
The value is given in analogy to the following substances: terpineol (p-menth-1-en-8ol)
Carcinogenicity No data available
Reproductive toxicity No data available
Specific target organ toxicity - single exposure No data available
Specific target organ toxicity - repeated exposure No data available
Aspiration hazard No data available
12. ECOLOGICAL INFORMATION
Ecotoxicity
No data available
Persistence and degradability
Colloidal silver
Toxicity to fish - semi-static test LC50 - Pimephales promelas (fathead minnow) - 0.0021 mg/l - 96 h
Remarks: (ECOTOX Database)
p-Menth-1-en-8-ol
Toxicity to fish - semi-static test LC50 - Danio rerio (zebra fish) - 62.3 mg/l - 96 h (OECD Test Guideline 203)
Toxicity to daphnia and other aquatic invertebrates static test EC50 - Daphnia magna (Water flea) - 83.3 mg/l - 48 h (OECD Test Guideline 202)
Toxicity to algae - static test ErC50 - Pseudokirchneriella subcapitata - 124 mg/l - 72 h (OECD Test Guideline 201) static test NOEC - Pseudokirchneriella subcapitata - 3.2 mg/l - 72 h (OECD Test Guideline 201)
Toxicity to fish - semi-static test LC50 - Pimephales promelas (fathead minnow) - 0.0021 mg/l - 96 h
Remarks: (ECOTOX Database)
p-Menth-1-en-8-ol
Toxicity to fish - semi-static test LC50 - Danio rerio (zebra fish) - 62.3 mg/l - 96 h (OECD Test Guideline 203)
Toxicity to daphnia and other aquatic invertebrates static test EC50 - Daphnia magna (Water flea) - 83.3 mg/l - 48 h (OECD Test Guideline 202)
Toxicity to algae - static test ErC50 - Pseudokirchneriella subcapitata - 124 mg/l - 72 h (OECD Test Guideline 201) static test NOEC - Pseudokirchneriella subcapitata - 3.2 mg/l - 72 h (OECD Test Guideline 201)
Bioaccumulative potential
No data available
Other adverse effects
No known side effects or critical hazards. Do not allow to enter drains or watercourses.
13. DISPOSAL CONSIDERATIONS
General information
The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.
Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.
Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
ADG label required
HAZCHEM
Carbon oxides Silver/silver oxides Mixture with combustible ingredients. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire.
Prevent fire extinguishing water from contaminating surface water or the ground water system.
Prevent fire extinguishing water from contaminating surface water or the ground water system.
UN Number
UN3077
Proper shipping name
Environmentally hazardous substance, solid, n.o.s. (colloidal silver)
Transport hazard class
3
Packing group
III
Environmental hazard
Yes
Special precautions for users
No information available.
Additional information
Incompatible materials: Oxygen, Strong acids and strong bases
15. REGULATORY INFORMATION
Poisons Schedule Number
No poison schedule number allocated
Other Information
No further relevant information available.
16. OTHER INFORMATION
SDS preparation date
21 February 2024
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.