SAFETY DATA SHEET
N,N-dimethylaniline
1. IDENTIFICATION
Product Identifiers
Product Name:
N,N-dimethylaniline
Other Names:
Not available
Product Number(s):
13360, EMS13360
CAS Number:
121-69-7
Recommended use of the chemical and restriction on use
Laboratory chemicals
Company Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
Emergency Contact Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS06 Skull and crossbones
Acute Toxicity - Oral 3 H301 Toxic if swallowed.
Acute Toxicity - Dermal 3 H311 Toxic in contact with the skin
Acute Toxicity - Inhalation 3 H331 Toxic if inhaled.
GHS08 Health hazard
Carcinogenicity 2 H351 Suspected of causing cancer.
Flammable liquids 4 H227 Combustible liquid.
Acute Toxicity - Oral 3 H301 Toxic if swallowed.
Acute Toxicity - Dermal 3 H311 Toxic in contact with the skin
Acute Toxicity - Inhalation 3 H331 Toxic if inhaled.
GHS08 Health hazard
Carcinogenicity 2 H351 Suspected of causing cancer.
Flammable liquids 4 H227 Combustible liquid.
Label Elements
Signal Words
Danger
Hazard Statement(s)
Combustible liquid.
Toxic if swallowed, in contact with skin or if inhaled.
Suspected of causing cancer.
Toxic if swallowed, in contact with skin or if inhaled.
Suspected of causing cancer.
Precautionary Statement(s)
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from flames and hot surfaces. - No smoking.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
Do not handle until all safety precautions have been read and understood.
Keep away from flames and hot surfaces. - No smoking.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
Primary route(s) of entry
Not available.
Human Health
Inhalation:
Remove person to fresh air and keep comfortable for breathing. If exposed or concerned: Get medical advice/attention.
Ingestion:
Immediately call a poison centre/doctor. Rinse mouth.
Eyes:
Call a poison centre/doctor if you feel unwell.
Skin:
Wash with plenty of water. Take off immediately all contaminated clothing and wash it before reuse.
Environment
In case of fire: Use CO₂, powder or water spray to extinguish.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION/INFORMATION ON INGREDIENTS
No information available.
4. FIRST AID MEASURES
Ingestion
Do not induce vomiting; immediately call for medical help.
Inhalation
Supply fresh air or oxygen; call for doctor.
In case of unconsciousness place patient stably in side position for transportation.
In case of unconsciousness place patient stably in side position for transportation.
Skin Contact
Immediately wash with water and soap and rinse thoroughly.
Eye Contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
Other Information
Immediately remove any clothing soiled by the product.
Remove breathing apparatus only after contaminated clothing have been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
Remove breathing apparatus only after contaminated clothing have been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
5. FIREFIGHTING MEASURES
Suitable extinguishing equipment
CO₂, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
HAZCHEM
No further relevant information available.
Special protective equipment and precautions for fire fighters
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Not required.
Environmental precautions
Inform respective authorities in case of seepage into water course or sewage system.
Dilute with plenty of water.
Do not allow to enter sewers/surface or ground water.
Dilute with plenty of water.
Do not allow to enter sewers/surface or ground water.
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
7. HANDLING AND STORAGE
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Keep respiratory protective device available.
Open and handle receptacle with care.
Keep respiratory protective device available.
Conditions for safe storage
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Standards
Material
TWA ppm
TWA mg/m3
STEL ppm
STEL mg/m3
121-69-7 N,N-dimethylaniline
5ppm
25mg/m³
10ppm
50mg/m³
Engineering controls
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Personal protective equipment
Eye and face protection
Goggles recommended during refilling.
Skin protection
Wear protective clothing.
Body protection
Protective gloves. The glove material has to be impermeable and resistant to the product/the substance/the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air.
9. PHYSICAL AND CHEMICAL PROPERTIES
General information
Appearance
Light yellow liquid
Odour
Characteristic
pH
7.4
Vapour Pressure
1hPa at 30°C
Density
0.956g/cm³ at 20°C
Boiling Point
193°C
Melting Point
1.5°C
Solubility
Fully miscible
Specific Gravity of Density
Not available
Flash Point
75°C
Flammable (Explosive) Limits
Lower: 1 Vol%
Upper: 7 Vol%
Upper: 7 Vol%
Ignition Temperature
370°C
Formula
C6H5N(CH3)2
10. STABILITY AND REACTIVITY
Reactivity
No further relevant information available.
Chemical stability
No decomposition if used according to specifications.
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No further relevant information available.
Incompatible materials
No further relevant information available.
11. TOXICOLOGICAL INFORMATION
Acute effects
Oral LD50 1410 mg/kg (rat)
Dermal LD50 1770 mg/kg (rabbit)
Dermal LD50 1770 mg/kg (rabbit)
Eye contact
No irritating effect.
Skin contact
No irritant effect.
Ingestion
Not available.
Inhalation
No sensitizing effects known.
Toxicity and irritation
Not available.
12. ECOLOGICAL INFORMATION
Ecotoxicity
Toxic for fish.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Water hazard class 3: extremely hazardous for water.
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxi for aquatic organisms.
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxi for aquatic organisms.
13. DISPOSAL CONSIDERATIONS
General information
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
Recommended cleansing agent: Water, if necessary with cleansing agents.
Disposal must be made according to official regulations.
Recommended cleansing agent: Water, if necessary with cleansing agents.
14. TRANSPORT INFORMATION
ADG label required
HAZCHEM
No further relevant information available.
UN Number
UN2253
Proper shipping name
2253 N,N-DIMETHYLANILINE, ENVIRONMENTALLY HAZARDOUS
Transport hazard class
Class 6.1 Toxic substances
Packing group
II
Environmental hazard
Environmentally hazardous substance, liquid; Marine Pollutant
Marine pollutant: Yes (DOT)
Symbol (fish and tree)
Marine pollutant: Yes (DOT)
Symbol (fish and tree)
Special precautions for users
Warning: Toxic substances
Hazard identification number (Kemler code): 60
EMS Number: F-A,S-A
Stowage Category: A
Hazard identification number (Kemler code): 60
EMS Number: F-A,S-A
Stowage Category: A
Additional information
DOT
Quantity limitation:
On passenger aircraft/rail: 5L
On cargo aircraft only: 60L
Hazardous substance: 100lbs, 45.4kg
Special marking with the symbol (fish and tree)
ADR
Excepted quantities (EQ) Code: E4
Maximum net quantity per inner packaging: 1mL
Maximum net quantity per outer packaging: 500mL
IMDG
Limited quantities (LQ) 100mL
Excepted quantities (EQ) Code: E4
Maximum net quantity per inner packaging: 1mL
Maximum net quantity per outer packaging: 500ml
Quantity limitation:
On passenger aircraft/rail: 5L
On cargo aircraft only: 60L
Hazardous substance: 100lbs, 45.4kg
Special marking with the symbol (fish and tree)
ADR
Excepted quantities (EQ) Code: E4
Maximum net quantity per inner packaging: 1mL
Maximum net quantity per outer packaging: 500mL
IMDG
Limited quantities (LQ) 100mL
Excepted quantities (EQ) Code: E4
Maximum net quantity per inner packaging: 1mL
Maximum net quantity per outer packaging: 500ml
15. REGULATORY INFORMATION
Poisons Schedule Number
Substance is not listed.
Other Information
A Chemical Safety Assessment has not been carried out.
16. OTHER INFORMATION
SDS preparation date
26 April 2023
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.