SAFETY DATA SHEET
Entellan New, mounting medium (DG)
1. IDENTIFICATION
Product Identifiers
Product Name:
Entellan New, mounting medium (DG)
Other Names:
Entellan mounting medium
Product Number(s):
EMS14800, EMS14802, IM022, IM0225
CAS Number:
1330-20-7
Recommended use of the chemical and restriction on use
In vitro diagnostic reagent, Reagent for analysis.
Company Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
Emergency Contact Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008)
Aquatic Chronic 3 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
Aquatic Chronic 3 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
Label Elements
Signal Words
Danger
Hazard Statement(s)
H225: Highly flammable liquid and vapour
H304: May be fatal if swallowed and enters airways
H315: Causes serious skin irritation
H336: May cause drowsiness or dizzeness
H361: Suspected of damaging fertility or the unborn child
H373: May cause damage to organs through prolonged or repeated exposure
H412: Harmful to aquatic life with long term effects
H304: May be fatal if swallowed and enters airways
H315: Causes serious skin irritation
H336: May cause drowsiness or dizzeness
H361: Suspected of damaging fertility or the unborn child
H373: May cause damage to organs through prolonged or repeated exposure
H412: Harmful to aquatic life with long term effects
Precautionary Statement(s)
P210: Keep away from flames and hot surfaces. No smoking
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P273: Avoid release to the environment
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301+P310: If swallowed: Immediately call a poison center/doctor
P303+P361+P353: If on skin (or hair) Take off immediately all contaminated clothing. Rinse skin with water/shower
P303+P351+P338: IF IN EYES Rinse cautiously with water for several minutes, Remove contact lenses, Continue rinsing
P312: Call a POISON center/doctor if you feel unwell
P405 Store locked up.
P501: Dispose of contents/container in accordance with local regional/national/international regulations.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P273: Avoid release to the environment
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301+P310: If swallowed: Immediately call a poison center/doctor
P303+P361+P353: If on skin (or hair) Take off immediately all contaminated clothing. Rinse skin with water/shower
P303+P351+P338: IF IN EYES Rinse cautiously with water for several minutes, Remove contact lenses, Continue rinsing
P312: Call a POISON center/doctor if you feel unwell
P405 Store locked up.
P501: Dispose of contents/container in accordance with local regional/national/international regulations.
Primary route(s) of entry
Inhalation, absorption through skin contact, ingestion
Human Health
Inhalation:
Harmful if inhaled
Ingestion:
May be fatal if swallowed
Eyes:
Not available.
Skin:
Causes serious skin irritation
Environment
Do not allow to enter sewers/ surface or ground water.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Name
CAS No.
Content (w/w)
Classification
Tolulene
108-88-3
>= 70 - < 90%
Flam. Liq. 2; 2; Repr. 2; STOT SE 3; STOT RE 2; Asp. Tox. 1; H225, H315, H361, H336, H373, H304Concentration limits: 20 %: STOT SE 3, H336;
4. FIRST AID MEASURES
Ingestion
After swallowing: caution if victim vomits. Risk of aspiration! Keep airways free. Pulmonary failure possible after aspiration of vomit. Call a physician immediately. Subsequently administer: activated charcoal (20 - 40 g in 10% slurry). More severe effects if alcohol is consumed
Inhalation
After inhalation: fresh air. If breathing stops: mouth-to-mouth breathing or artificial respiration. Oxygen if necessary. Immediately call in physician.
Skin Contact
After skin contact: wash off with plenty of water. Remove contaminated clothing. Consult a physician.
Eye Contact
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.
Other Information
Most important symptoms and effects, both acute and delayed irritant effects,
Dermatitis, Dizziness, narcosis, euphoria, agitation, Gastrointestinal disturbance,
Headache, Convulsions, drowziness
Drying-out effect resulting in rough and chapped skin.
Dermatitis, Dizziness, narcosis, euphoria, agitation, Gastrointestinal disturbance,
Headache, Convulsions, drowziness
Drying-out effect resulting in rough and chapped skin.
5. FIREFIGHTING MEASURES
Suitable extinguishing equipment
Foam, Carbon dioxide (CO₂)
** For this substance/mixture no limitations of extinguishing agents are given.
HAZARDS ARISING FROM MIXTURE:
Carbon oxides
Combustible.
Pay attention to flashback.
Vapors are heavier than air and may spread along floors.
Development of hazardous combustion gases or vapours possible in the event of fire.
Forms explosive mixtures with air at ambient temperatures.
Remove container from danger zone and cool with water
Prevent fire extinguishing water from contaminating surface water or the ground water system
Do not let product enter drains.
Risk of explosion.
** For this substance/mixture no limitations of extinguishing agents are given.
HAZARDS ARISING FROM MIXTURE:
Carbon oxides
Combustible.
Pay attention to flashback.
Vapors are heavier than air and may spread along floors.
Development of hazardous combustion gases or vapours possible in the event of fire.
Forms explosive mixtures with air at ambient temperatures.
Remove container from danger zone and cool with water
Prevent fire extinguishing water from contaminating surface water or the ground water system
Do not let product enter drains.
Risk of explosion.
HAZCHEM
*3Y
Special protective equipment and precautions for fire fighters
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel:
Do not breathe vapours, aerosols.
Avoid substance contact.
Ensure adequate ventilation.
Keep away from heat and sources of ignition.
Evacuate the danger area, observe emergency procedures, consult an expert.
Advice for emergency responders: Protective equipment see section 8.
Do not breathe vapours, aerosols.
Avoid substance contact.
Ensure adequate ventilation.
Keep away from heat and sources of ignition.
Evacuate the danger area, observe emergency procedures, consult an expert.
Advice for emergency responders: Protective equipment see section 8.
Environmental precautions
Do not let product enter drains. Risk of explosion.
Methods and materials for containment and clean up
Cover drains
Collect, bind, and pump off spills.
Observe possible material restrictions (see sections 7 and 10)
Take up with liquid-absorbent material (e.g. Chemizorb® ).
Dispose of properly
Clean up affected area.
Collect, bind, and pump off spills.
Observe possible material restrictions (see sections 7 and 10)
Take up with liquid-absorbent material (e.g. Chemizorb® ).
Dispose of properly
Clean up affected area.
7. HANDLING AND STORAGE
Precautions for safe handling
Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Conditions for safe storage
Keep away from heat and sources of ignition.
Store at +15°C to +25°C.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Standards
Material
TWA ppm
TWA mg/m3
STEL ppm
STEL mg/m3
Tolulene (108-88-3)
50 ppm
188 mg/m³
-
-
Engineering controls
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
Personal protective equipment
Eye and face protection
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Skin protection
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
Full contact
Material: Viton®
Minimum layer thickness: 0.7 mm
Break through time: > 480 min
Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M)
Full contact
Material: Viton®
Minimum layer thickness: 0.7 mm
Break through time: > 480 min
Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M)
Body protection
Flame retardant antistatic protective clothing. The chemical resistance of the protective equipment should be enquired at the respective supplier.
Respiratory protection
Required when vapours/aerosols are generated.
Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented
Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented
9. PHYSICAL AND CHEMICAL PROPERTIES
General information
Appearance
Liquid colourless
Odour
Characteristic
pH
Not available.
Vapour Pressure
No data available
Density
No data available
Boiling Point
No data available
Melting Point
No data available
Solubility
at 20 °C practically insoluble
Specific Gravity of Density
No data available
Flash Point
8 °C
Flammable (Explosive) Limits
Not classified as explosive.
Ignition Temperature
No data available
Formula
Viscosity, kinematic: No data available
Viscosity, dynamic: 60 - 100 mPa.s at 20 °C
Viscosity, dynamic: 60 - 100 mPa.s at 20 °C
10. STABILITY AND REACTIVITY
Reactivity
Vapors may form explosive mixture with air.
Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
Possibility of hazardous reactions
Risk of explosion with:
fuming sulphuric acid
Nitric acid
silver
perchlorates
nitrogen dioxide
halogen-halogen compounds
uranium hexafluoride
organic nitro compounds
nonmetallic halides
acetic acid
Violent reactions possible with:
Strong oxidising agents
Strong acids
sulphur
fuming sulphuric acid
Nitric acid
silver
perchlorates
nitrogen dioxide
halogen-halogen compounds
uranium hexafluoride
organic nitro compounds
nonmetallic halides
acetic acid
Violent reactions possible with:
Strong oxidising agents
Strong acids
sulphur
Conditions to avoid
Heating
Incompatible materials
Rubber, various plastics
11. TOXICOLOGICAL INFORMATION
Acute effects
Systemic effects: Headache, Drowziness, Dizziness, Euphoria, Agitation, Convulsions, Narcosis
Suspected of damaging the unborn child.
Suspected of damaging fertility.
Mixture may cause damage to organs through prolonged or repeated exposure. - Central
nervous system
Suspected of damaging the unborn child.
Suspected of damaging fertility.
Mixture may cause damage to organs through prolonged or repeated exposure. - Central
nervous system
Eye contact
Slight irritation
Skin contact
Mixture causes skin irritation.
Drying-out effect resulting in rough and chapped skin. After long-term exposure to the chemical:
Dermatitis
Drying-out effect resulting in rough and chapped skin. After long-term exposure to the chemical:
Dermatitis
Ingestion
Gastrointestinal disturbance, Risk of aspiration upon vomiting.
Inhalation
Aspiration hazard, Aspiration may cause pulmonary edema and pneumonitis.
Mixture may cause drowsiness or dizziness.
Mixture may cause drowsiness or dizziness.
Toxicity and irritation
Acute toxicity
LD50 Oral - Rat - male - 5,580 mg/kg
(Tested according to Directive 92/69/EEC.)
LC50 Inhalation - Rat - male and female - 4 h - 25.7 mg/l - vapour
(OECD Test Guideline 403)
LD50 Dermal - Rabbit - > 5,000 mg/kg
Remarks: (ECHA)
Skin corrosion/irritation
Skin - Rabbit
Result: irritating - 4 h
Remarks: (ECHA)
Serious eye damage/eye irritation
Eyes - Rabbit
Result: slight irritation
(OECD Test Guideline 405)
Respiratory or skin sensitization
Maximization Test - Guinea pig
Result: negative
(Regulation (EC) No. 440/2008, Annex, B.6)
Germ cell mutagenicity
Test Type: In vitro mammalian cell gene mutation test
Test system: Mouse lymphoma test
Result: negative
Test Type: Ames test
Test system: S. typhimurium
Result: negative
Species: Rat - Bone marrow
Result: negative
Remarks: (ECHA)
Carcinogenicity
No data available
Reproductive toxicity
Suspected of damaging the unborn child.
Specific target organ toxicity - single exposure
May cause drowsiness or dizziness. - Central nervous system
Specific target organ toxicity - repeated exposure
May cause damage to organs through prolonged or repeated exposure. - Central nervous system
LD50 Oral - Rat - male - 5,580 mg/kg
(Tested according to Directive 92/69/EEC.)
LC50 Inhalation - Rat - male and female - 4 h - 25.7 mg/l - vapour
(OECD Test Guideline 403)
LD50 Dermal - Rabbit - > 5,000 mg/kg
Remarks: (ECHA)
Skin corrosion/irritation
Skin - Rabbit
Result: irritating - 4 h
Remarks: (ECHA)
Serious eye damage/eye irritation
Eyes - Rabbit
Result: slight irritation
(OECD Test Guideline 405)
Respiratory or skin sensitization
Maximization Test - Guinea pig
Result: negative
(Regulation (EC) No. 440/2008, Annex, B.6)
Germ cell mutagenicity
Test Type: In vitro mammalian cell gene mutation test
Test system: Mouse lymphoma test
Result: negative
Test Type: Ames test
Test system: S. typhimurium
Result: negative
Species: Rat - Bone marrow
Result: negative
Remarks: (ECHA)
Carcinogenicity
No data available
Reproductive toxicity
Suspected of damaging the unborn child.
Specific target organ toxicity - single exposure
May cause drowsiness or dizziness. - Central nervous system
Specific target organ toxicity - repeated exposure
May cause damage to organs through prolonged or repeated exposure. - Central nervous system
12. ECOLOGICAL INFORMATION
Ecotoxicity
Toxicity to fish flow-through test LC50 - Oncorhynchus kisutch (coho salmon) -
5.5 mg/l - 96 h
Remarks: (ECHA)
Toxicity to daphnia
and other aquatic
invertebrates
EC50 - Ceriodaphnia dubia (water flea) - 3.78 mg/l - 48 h
(US-EPA)
Toxicity to bacteria static test EC50 - Bacteria - 84 mg/l - 24 h
Remarks: (ECHA)
5.5 mg/l - 96 h
Remarks: (ECHA)
Toxicity to daphnia
and other aquatic
invertebrates
EC50 - Ceriodaphnia dubia (water flea) - 3.78 mg/l - 48 h
(US-EPA)
Toxicity to bacteria static test EC50 - Bacteria - 84 mg/l - 24 h
Remarks: (ECHA)
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Discharge into the environment must be avoided.
13. DISPOSAL CONSIDERATIONS
General information
Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself.
14. TRANSPORT INFORMATION
ADG label required
HAZCHEM
*3Y
UN Number
UN1866
Proper shipping name
Resin solution
Transport hazard class
3
Packing group
PG II
Environmental hazard
No information available
Special precautions for users
· Warning: Flammable liquids
· Hazard identification number (Kemler code): 30
· EMS Number: F-E,S-E
· Stowage Category A
· Hazard identification number (Kemler code): 30
· EMS Number: F-E,S-E
· Stowage Category A
Additional information
Quantity limitations On passenger aircraft/rail: 60 L
On cargo aircraft only: 220 L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 mL
Maximum net quantity per outer packaging: 1000 mL
· Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 mL
Maximum net quantity per outer packaging: 1000 mL
On cargo aircraft only: 220 L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 mL
Maximum net quantity per outer packaging: 1000 mL
· Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 mL
Maximum net quantity per outer packaging: 1000 mL
15. REGULATORY INFORMATION
Poisons Schedule Number
-
Other Information
-
16. OTHER INFORMATION
SDS preparation date
31 August 2022
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.
This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.