SAFETY DATA SHEET
Glutaraldehyde 50% solution, Bio. Grade (DG)
1. IDENTIFICATION
Product Identifiers
Product Name:
Glutaraldehyde 50% solution, Bio. Grade (DG)
Other Names:
N/A
Product Number(s):
16500, 16501, 16520, 16521, EMS16500, EMS16501, EMS16520, EMS16521
CAS Number:
111-30-8
Recommended use of the chemical and restriction on use
Laboratory use
Company Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
Emergency Contact Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS08 Health hazard
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
GHS05 Corrosion
Skin Corr. 1C H314 Causes severe skin burns and eye damage.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H332 Harmful if inhaled.
Skin Sens. 1B H317 May cause an allergic skin reaction.
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
GHS05 Corrosion
Skin Corr. 1C H314 Causes severe skin burns and eye damage.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H332 Harmful if inhaled.
Skin Sens. 1B H317 May cause an allergic skin reaction.
Label Elements
Signal Words
Danger
Hazard Statement(s)
Harmful if swallowed or if inhaled.
Causes severe skin burns and eye damage.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Causes severe skin burns and eye damage.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Precautionary Statement(s)
Do not breathe dusts or mists.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
[In case of inadequate ventilation] wear respiratory protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If swallowed: Rinse mouth. Do NOT induce vomiting.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
If skin irritation or rash occurs: Get medical advice/attention.
If experiencing respiratory symptoms: Call a poison center/doctor.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
[In case of inadequate ventilation] wear respiratory protection.
If swallowed: Call a poison center/doctor if you feel unwell.
If swallowed: Rinse mouth. Do NOT induce vomiting.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
Specific treatment (see on this label).
If skin irritation or rash occurs: Get medical advice/attention.
If experiencing respiratory symptoms: Call a poison center/doctor.
Wash contaminated clothing before reuse.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Primary route(s) of entry
No further relevant information available.
Human Health
Inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation
In case of unconsciousness place patient stably in side position for transportation
Ingestion:
Immediately call a doctor.
Drink copious amounts of water and provide fresh air
Drink copious amounts of water and provide fresh air
Eyes:
Rinse opened eye for several minutes under running water. Then consult a doctor
Skin:
Immediately remove any clothing soiled by the product. Immediately wash with water and soap and rinse thoroughly
Environment
Water hazard class 3 (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms
3. COMPOSITION/INFORMATION ON INGREDIENTS
Name
CAS No.
Content (w/w)
Classification
Glutaraldehyde
111-30-8
>25-≤50%
Mixtures
4. FIRST AID MEASURES
Ingestion
Immediately call a doctor. Drink copious amounts of water and provide fresh air.
Inhalation
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
In case of unconsciousness place patient stably in side position for transportation.
Skin Contact
Immediately remove any clothing soiled by the product. Immediately wash with water and soap and rinse thoroughly.
Eye Contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
Other Information
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may occur after several hours; therefore medical observation for at least 48 hours after the accident.
Symptoms of poisoning may occur after several hours; therefore medical observation for at least 48 hours after the accident.
5. FIREFIGHTING MEASURES
Suitable extinguishing equipment
Use fire fighting measures that suit the environment.
HAZCHEM
No further relevant information available
Special protective equipment and precautions for fire fighters
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Environmental precautions
Inform respective authorities in case of seepage into water course or sewage system.
Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water
Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation
7. HANDLING AND STORAGE
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Prevent formation of aerosols.
Conditions for safe storage
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Standards
Material
TWA ppm
TWA mg/m3
STEL ppm
STEL mg/m3
111-30-8 Glutaraldehyde
0.2ppm
0.8mg/m³
0.05ppm
0.2 mg/m³
Engineering controls
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Personal protective equipment
Eye and face protection
Tightly sealed goggles
Skin protection
Protective gloves - The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Body protection
No further relevant information available
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
respiratory protective device that is independent of circulating air.
9. PHYSICAL AND CHEMICAL PROPERTIES
General information
Appearance
Clear liquid
Odour
Acrid
pH
Not determined
Vapour Pressure
at 20 °C (68 °F): 23 hPa (17.3 mm Hg)
Density
at 20 °C (68 °F): 1.1 g/cm³ (9.1795 lbs/gal)
Boiling Point
100.6 °C (213.1 °F)
Melting Point
Undetermined
Solubility
Fully miscible.
Specific Gravity of Density
Not determined.
Flash Point
Not determined.
Flammable (Explosive) Limits
Not determined.
Ignition Temperature
Not determined.
Formula
Solvent content:
Organic solvents: 0.3 %
Water: 49.8 %
VOC content: 0.25 %
6.1 g/l / 0.05 lb/gal
Organic solvents: 0.3 %
Water: 49.8 %
VOC content: 0.25 %
6.1 g/l / 0.05 lb/gal
10. STABILITY AND REACTIVITY
Reactivity
No further relevant information available
Chemical stability
Stable under normal working laboratory conditions
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No further relevant information available
Incompatible materials
No further relevant information available
11. TOXICOLOGICAL INFORMATION
Acute effects
No further relevant information available
Eye contact
Strong caustic effect.
Skin contact
Strong caustic effect on skin and mucous membranes. Sensitization possible through skin contact.
Ingestion
Not determined.
Inhalation
Sensitization possible through inhalation
Toxicity and irritation
LD/LC50 values that are relevant for classification:
111-30-8 Glutaraldehyde
Oral LD50 134 mg/kg (rat)
Dermal LD50 2,560 mg/kg (rabbit)
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
111-30-8 Glutaraldehyde
Oral LD50 134 mg/kg (rat)
Dermal LD50 2,560 mg/kg (rabbit)
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
12. ECOLOGICAL INFORMATION
Ecotoxicity
Water hazard class 3 (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Water hazard class 3: extremely hazardous for water.
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Must not reach sewage water or drainage ditch undiluted or unneutralised.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms.
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Must not reach sewage water or drainage ditch undiluted or unneutralised.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms.
13. DISPOSAL CONSIDERATIONS
General information
Must not be disposed together with household garbage. Do not allow product to reach sewage system. Disposal must be made according to official regulations.
Recommended cleansing agents: Water, if necessary together with cleansing agents.
Recommended cleansing agents: Water, if necessary together with cleansing agents.
14. TRANSPORT INFORMATION
ADG label required
HAZCHEM
No further relevant information available
UN Number
UN3265
Proper shipping name
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S (Glutaraldehyde), ENVIRONMENTALLY HAZARDOUS
Transport hazard class
8 Corrosive substances
Packing group
PG III
Environmental hazard
Product contains environmentally hazardous substances: Glutaraldehyde
Special precautions for users
Warning: Corrosive substances
Additional information
· Danger code (Kemler): 886
· EMS Number: F-A,S-B
· Segregation groups Acids
· Stowage Category B
· Stowage Code SW2 Clear of living quarters.
Quantity limitations On passenger aircraft/rail: 0.5 L
On cargo aircraft only: 2.5 L
Excepted quantities (EQ) Code: E1
Not permitted as Excepted Quantity
Maximum net quantity per inner packaging: 30 mL
Maximum net quantity per outer packaging: 1000 mL
· EMS Number: F-A,S-B
· Segregation groups Acids
· Stowage Category B
· Stowage Code SW2 Clear of living quarters.
Quantity limitations On passenger aircraft/rail: 0.5 L
On cargo aircraft only: 2.5 L
Excepted quantities (EQ) Code: E1
Not permitted as Excepted Quantity
Maximum net quantity per inner packaging: 30 mL
Maximum net quantity per outer packaging: 1000 mL
15. REGULATORY INFORMATION
Poisons Schedule Number
111-30-8 Glutaraldehyde S2, S5, S6
67-56-1 Methyl Alcohol S5, S6
67-56-1 Methyl Alcohol S5, S6
Other Information
Section 313 (Specific toxic chemical listings):
67-56-1 Methyl Alcohol
Chemicals known to cause developmental toxicity:
67-56-1 Methyl Alcohol
TLV (Threshold Limit Value established by ACGIH)
111-30-8 Glutaraldehyde A4
67-56-1 Methyl Alcohol
Chemicals known to cause developmental toxicity:
67-56-1 Methyl Alcohol
TLV (Threshold Limit Value established by ACGIH)
111-30-8 Glutaraldehyde A4
16. OTHER INFORMATION
SDS preparation date
12 January 2023
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.
This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.