SAFETY DATA SHEET
Glutaraldehyde and Formaldehyde 3% Solution in 0.1M Sodium Cacodylate Buffer pH 7.4
1. IDENTIFICATION
Product Identifiers
Product Name:
Glutaraldehyde and Formaldehyde 3% Solution in 0.1M Sodium Cacodylate Buffer pH 7.4
Other Names:
Formaldehyde/Glutaraldehyde, 3% in 0.1M Sod. Cac. Buffer, pH 7.4
Product Number(s):
15950, 16538-SPP, CEMS15950
CAS Number:
Not available
Recommended use of the chemical and restriction on use
Laboratory chemicals
Company Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
Emergency Contact Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS08 Health hazard
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Muta. 2 H341 suspected of causing genetic defects.
Carc. 1B H350 May cause cancer.
GHS05 Corrosion
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Acute Tox. 4 H332 Harmful if inhaled.
Skin Irrit. 2 H315 Causes skin irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H335 May cause respiratory irritation.
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Muta. 2 H341 suspected of causing genetic defects.
Carc. 1B H350 May cause cancer.
GHS05 Corrosion
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Acute Tox. 4 H332 Harmful if inhaled.
Skin Irrit. 2 H315 Causes skin irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
STOT SE 3 H335 May cause respiratory irritation.
Label Elements
Signal Words
Danger
Hazard Statement(s)
Harmful if inhaled.
Causes skin irritation.
Causes serious eye damage.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Suspected of causing genetic defects.
May cause cancer.
May cause respiratory irritation.
Causes skin irritation.
Causes serious eye damage.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Suspected of causing genetic defects.
May cause cancer.
May cause respiratory irritation.
Precautionary Statement(s)
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
Wear respiratory protection.
Do not handle until all safety precautions have been read and understood.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
Wear respiratory protection.
Primary route(s) of entry
Not available.
Human Health
Inhalation:
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms call a POISON CENTRE/Doctor.
Ingestion:
Not available.
Eyes:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. continue rinsing.
Skin:
Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation or rash occurs get medical advice/attention.
Environment
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Name
CAS No.
Content (w/w)
Classification
Formaldehyde
50-00-0
>2.5-≤10%
Mixtures
Glutaraldehyde
111-30-8
>2.5-≤10%
Mixtures
Sodium dimethylarsinate
124-65-2
≤2.5%
Mixtures
4. FIRST AID MEASURES
Ingestion
Call for a doctor immediately.
Inhalation
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation
In case of unconsciousness place patient stably in side position for transportation
Skin Contact
Immediately wash with water and soap and rinse thoroughly.
Eye Contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
Other Information
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
5. FIREFIGHTING MEASURES
Suitable extinguishing equipment
Use fire extinguishing methods suitable to surrounding conditions.
HAZCHEM
No further relevant information available.
Special protective equipment and precautions for fire fighters
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Not required.
Environmental precautions
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/surface or ground water.
Do not allow to enter sewers/surface or ground water.
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
7. HANDLING AND STORAGE
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Keep respiratory protective device available.
Open and handle receptacle with care.
Prevent formation of aerosols.
Keep respiratory protective device available.
Conditions for safe storage
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Standards
Material
TWA ppm
TWA mg/m3
STEL ppm
STEL mg/m3
Formaldehyde
1ppm
1.2mg/m³
2ppm
2.5mg/m³
Glutaraldehyde
0.1ppm
0.41mg/m³
-
Sodium dimethylarsinate
0.05mg/m³
-
Engineering controls
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the skin.
Avoid contact with the eyes and skin.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the skin.
Avoid contact with the eyes and skin.
Personal protective equipment
Eye and face protection
Tightly sealed goggles.
Skin protection
Wear protective gloves. The glove material has to be impermeable and resistant to the product/the substance/the preparation. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Body protection
Not available
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
9. PHYSICAL AND CHEMICAL PROPERTIES
General information
Appearance
Transparent liquid.
Odour
Specific type
pH
7.4
Vapour Pressure
23hPa at 20°C
Density
Not determined.
Boiling Point
100°C
Melting Point
Undetermined
Solubility
Not miscible or difficult to mix.
Specific Gravity of Density
Not determined.
Flash Point
Not applicable
Flammable (Explosive) Limits
Not determined
Ignition Temperature
Product is not selfigniting
Formula
Not available.
10. STABILITY AND REACTIVITY
Reactivity
No further relevant information available.
Chemical stability
No decomposition if used according to specifications.
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No further relevant information available.
Incompatible materials
No further relevant information available.
11. TOXICOLOGICAL INFORMATION
Acute effects
Not available.
Eye contact
Strong irritant with the danger of severe eye injury.
Skin contact
Irritant to skin and mucous membranes.
Ingestion
Not available
Inhalation
Sensitisation possible through inhalation.
Sensitisation possible through skin contact.
Sensitisation possible through skin contact.
Toxicity and irritation
Harmful
Irritant
Carcinogenic
Irritant
Carcinogenic
12. ECOLOGICAL INFORMATION
Ecotoxicity
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Toxic for fish.
harmful to fish.
Water hazard class 3: extremely hazardous for water.
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms.
Harmful to aquatic organisms.
harmful to fish.
Water hazard class 3: extremely hazardous for water.
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms.
Harmful to aquatic organisms.
13. DISPOSAL CONSIDERATIONS
General information
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
Disposal must be made according to official regulations.
14. TRANSPORT INFORMATION
ADG label required
HAZCHEM
No further relevant information available.
UN Number
UN1760
Proper shipping name
14760 CORROSIVE LIQUID, N.O.S. (Glutaraldehyde, FORMALDEHYDE SOLUTION)
Transport hazard class
Class: 8 Corrosive substances.
Packing group
II
Environmental hazard
Not applicable.
Special precautions for users
Warning: Corrosive substances.
Hazard identification number (Kemler code): 80
EMS Number: F-A,S-B
Segregation groups: Acids
Stowage Category: B
Stowage Code: SW2 Clear of living quarters.
Hazard identification number (Kemler code): 80
EMS Number: F-A,S-B
Segregation groups: Acids
Stowage Category: B
Stowage Code: SW2 Clear of living quarters.
Additional information
Limited quantities (LQ) 1L
Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30mL
Maximum net quantity per outer packaging: 500mL
Transport category 2
Tunnel restriction code E
Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30mL
Maximum net quantity per outer packaging: 500mL
Transport category 2
Tunnel restriction code E
15. REGULATORY INFORMATION
Poisons Schedule Number
Formaldehyde S2, S6, S10
Other Information
Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation.
Exceptions can be made by the authorities in certain cases.
Exceptions can be made by the authorities in certain cases.
16. OTHER INFORMATION
SDS preparation date
13 December 2022
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.