SAFETY DATA SHEET
Fomblin® 06/6
1. IDENTIFICATION
Product Identifiers
Product Name:
Fomblin® 06/6
Other Names:
Fluoropolymer, Mixture of (S) parafluoropropene and oxygen polymerised, amide derivative and Propene, 1,1,2,3,3,3 hexafluoro, oxidised, polymerised.
Product Number(s):
N/A
CAS Number:
69991-67-9
Recommended use of the chemical and restriction on use
Laboratory use.
For use in vacuum pumps.
For use in vacuum pumps.
Company Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
Emergency Contact Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
No information available.
Label Elements
Signal Words
Warning
Hazard Statement(s)
Clear, colourless liquid. Thermal decomposition will generate hydrogen fluoride (HF), which is corrosive.
Precautionary Statement(s)
Not available.
Primary route(s) of entry
Not available.
Human Health
Inhalation:
Inhalation of vapours or mists may cause respiratory tract irritation.
Ingestion:
Not an expected exposure route. Ingestion may cause nausea and vomiting.
Eyes:
Eye contact may cause slight irritation.
Skin:
Skin contact may cause slight irritation.
Environment
Not available.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Name
CAS No.
Content (w/w)
Classification
Propene, 1,1,2,3,3,3-hexafluoro, oxidised, polymerised
69991- 67-9
100
-
4. FIRST AID MEASURES
Ingestion
If conscious, drink three to four 8 ounce glasses of water or milk. Call a physician. If unconscious, immediately take affected person to a hospital. Do not give anything by mouth to an unconscious person.
Inhalation
If symptoms of irritation, discomfort or overcome by exposure, remove affected person to fresh air. Give oxygen or artificial respiration as needed.
Skin Contact
Wash skin thoroughly with mild soap and water. Flush with lukewarm water for 15 minutes.
Eye Contact
Flush eyes for 15 minutes with copious amounts of water, retracting eyelids often. Seek medical attention if irritation persists.
Other Information
No further relevant information available.
5. FIREFIGHTING MEASURES
Suitable extinguishing equipment
Water (spray or fog), foam, dry chemical or carbon dioxide (CO₂).
HAZCHEM
Fluoropolymers will degrade upon prolonged heating or in a fire, liberating carbonyl fluoride and hydrogen fluoride (HF). This gas is toxic if inhaled or it comes into contact with moist skin.
HF has an ACGIH TLV ceiling limit of 3 ppm (2.6 mg/m3) and an
OSHA PEL TWA of 3 ppm.
Carbonyl fluoride has an ACGIH TLV TWA and OSHA
PEL TWA of 2 ppm (5 mg/m3).
HF has an ACGIH TLV ceiling limit of 3 ppm (2.6 mg/m3) and an
OSHA PEL TWA of 3 ppm.
Carbonyl fluoride has an ACGIH TLV TWA and OSHA
PEL TWA of 2 ppm (5 mg/m3).
Special protective equipment and precautions for fire fighters
Do not enter fire area without proper protection. Fight fire from a safe distance. If possible, air monitoring should be performed.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Extinguish all ignition sources and evacuate the area. Exercise caution; spill area may be slippery.
Environmental precautions
Not available.
Methods and materials for containment and clean up
In case of a release or spill, absorb material onto vermiculite or similar inert absorbent.
Use Perfluorosolv0 PFS1 Solvent to clean any residual material. Place spilled material into covered container for disposal. Dispose of according to applicable local, state and federal regulations.
Use Perfluorosolv0 PFS1 Solvent to clean any residual material. Place spilled material into covered container for disposal. Dispose of according to applicable local, state and federal regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Wash hands after use and before handling food or applying cosmetics. Do not use tobacco products in the immediate area.
Conditions for safe storage
sparks and flames. Do not store near combustible materials.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Standards
Engineering controls
Local Exhaust: Vent vapours or mists generated by processing away from operating personnel. Local exhaust ventilation at a rate of 50 feet per minute.
Personal protective equipment
Eye and face protection
Not available.
Skin protection
Rubber or latex gloves recommended but not necessary.
Body protection
Not available.
Respiratory protection
No occupational exposure standards have been developed for this material. In situations where exposure to vapours or mists is likely, NIOSH/MSHA approved respirators are recommended. Respirator use limitations made by NIOSH/MSHA or the manufacturer must be observed. Respiratory protection programs must be in accordance with 29 CFR 1910.134.
9. PHYSICAL AND CHEMICAL PROPERTIES
General information
Appearance
Colourless clear liquid
Odour
Odorless
pH
Not available.
Vapour Pressure
Not available.
Density
1.7 - 1.9
Boiling Point
Not available.
Melting Point
Not available.
Solubility
Water: Insoluble
Specific Gravity of Density
Not available.
Flash Point
Not applicable.
Flammable (Explosive) Limits
Not applicable.
Ignition Temperature
Not Applicable.
Formula
CF3-[(O-CF-CF3-CF2)n-(O-CF2)m]-O-CF3
10. STABILITY AND REACTIVITY
Reactivity
This material is not reactive.
Chemical stability
This material is stable.
Possibility of hazardous reactions
Thermal decomposition of this product will generate hydrogen fluoride (HF), which is corrosive, causing burns on contact with skin and other tissue.
Conditions to avoid
Strong or non-aqueous alkali or Lewis acids above 100o C/212o F.
Incompatible materials
Alkali metals and halogenated compounds.
11. TOXICOLOGICAL INFORMATION
Acute effects
Rat oral LD50: greater than 25.65 g/kg
Rat intraperitoneal LD50: greater than 25 g/kg
Rat dermal LD50: greater than 2 g/kg
Rat intraperitoneal LD50: greater than 25 g/kg
Rat dermal LD50: greater than 2 g/kg
Eye contact
No further relevant information available.
Skin contact
No further relevant information available.
Ingestion
No further relevant information available.
Inhalation
No further relevant information available.
Toxicity and irritation
Rabbit skin irritation: not irritating.
Rabbit eye irritation: not irritating.
Guinea pig sensitization: not a sensitiser .
Rabbit eye irritation: not irritating.
Guinea pig sensitization: not a sensitiser .
12. ECOLOGICAL INFORMATION
Ecotoxicity
No ecotoxicological information is available for this material.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
No further relevant information available.
13. DISPOSAL CONSIDERATIONS
General information
All components of this product are listed on the Toxic Substances Control Act (TSCA)
Section 8(b) Chemical Inventory and the Canadian Environmental Protection Act
(CEPA) provisional domestic substances list (DSL). This product is not a "hazardous
substance" as defined by OSHA Hazard Communication Standard (29 CFR 1910.1200).
This product is not a "controlled product" as defined by the Canadian Workplace
Hazardous Materials Information System (WHMIS)
Section 8(b) Chemical Inventory and the Canadian Environmental Protection Act
(CEPA) provisional domestic substances list (DSL). This product is not a "hazardous
substance" as defined by OSHA Hazard Communication Standard (29 CFR 1910.1200).
This product is not a "controlled product" as defined by the Canadian Workplace
Hazardous Materials Information System (WHMIS)
14. TRANSPORT INFORMATION
ADG label required
HAZCHEM
Fluoropolymers will degrade upon prolonged heating or in a fire, liberating carbonyl fluoride and hydrogen fluoride (HF). This gas is toxic if inhaled or it comes into contact with moist skin.
HF has an ACGIH TLV ceiling limit of 3 ppm (2.6 mg/m3) and an
OSHA PEL TWA of 3 ppm.
Carbonyl fluoride has an ACGIH TLV TWA and OSHA
PEL TWA of 2 ppm (5 mg/m3).
HF has an ACGIH TLV ceiling limit of 3 ppm (2.6 mg/m3) and an
OSHA PEL TWA of 3 ppm.
Carbonyl fluoride has an ACGIH TLV TWA and OSHA
PEL TWA of 2 ppm (5 mg/m3).
UN Number
None
Proper shipping name
Not regulated.
Transport hazard class
Void
Packing group
None.
Environmental hazard
No information available.
Special precautions for users
No information available.
Additional information
No information available.
15. REGULATORY INFORMATION
Poisons Schedule Number
Not listed.
Other Information
No further relevant information available.
16. OTHER INFORMATION
SDS preparation date
22 February 2018
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.