SAFETY DATA SHEET
JB-4 Solution B
1. IDENTIFICATION
Product Identifiers
Product Name:
JB-4 Solution B
Other Names:
N,N-Dimethylaniline [Benzenamine, N,Ndimethyl]
Product Number(s):
C612, C617
CAS Number:
Not available.
Recommended use of the chemical and restriction on use
Laboratory use.
Company Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
Emergency Contact Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS07
Acute Tox. 4 H312 Harmful In contact with skin.
Acute Tox. 4 H332 Harmful if inhaled.
Skin Irrit. 2 H315 Causes skin irritation.
Acute Tox. 4 H312 Harmful In contact with skin.
Acute Tox. 4 H332 Harmful if inhaled.
Skin Irrit. 2 H315 Causes skin irritation.
Label Elements
Signal Words
Warning
Hazard Statement(s)
Harmful in contact with skin or if inhaled.
Causes skin irritation.
Causes skin irritation.
Precautionary Statement(s)
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing.
Primary route(s) of entry
Not available.
Human Health
Inhalation:
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison centre/doctor if you feel unwell.
Ingestion:
Call a POISON CENTER/doctor if you feel unwell.
Specific treatment (see on this label).
Rinse mouth.
Specific treatment (see on this label).
Rinse mouth.
Eyes:
Not available.
Skin:
Wash with plenty of water.
If skin irritation or rash occurs: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse.'
Wash contaminated clothing before reuse.
If skin irritation or rash occurs: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse.'
Wash contaminated clothing before reuse.
Environment
Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Name
CAS No.
Content (w/w)
Classification
N,N-dimethylaniline
121-69-7
2.5-10%
-
acetaldehyde
75-07-0
≤ 2.5%
-
ethylene oxide
75-21-8
≤ 2.5%
-
formaldehyde
50-00-0
≤ 2.5%
-
1,4-dioxane
123-91-1
≤ 2.5%
-
Polyethylene glycol
25322-68-3
>50-≤100%
4. FIRST AID MEASURES
Ingestion
Call for a doctor immediately.
Inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist. In case of unconsciousness place patient stably in side position for transportation.
Skin Contact
Immediately wash with water and soap and rinse thoroughly.
Eye Contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
Other Information
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
5. FIREFIGHTING MEASURES
Suitable extinguishing equipment
CO₂, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
HAZCHEM
No further relevant information available.
Special protective equipment and precautions for fire fighters
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Not required.
Environmental precautions
Dilute with plenty of water.
Do not allow to enter sewers/surface or ground water.
Do not allow to enter sewers/surface or ground water.
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation
Ensure adequate ventilation
7. HANDLING AND STORAGE
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols
Prevent formation of aerosols
Conditions for safe storage
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Standards
Material
TWA ppm
TWA mg/m3
STEL ppm
STEL mg/m3
N,N-dimethylaniline
5 ppm
25 mg/m³
10 ppm
50 mg/m³
acetaldehyde
20 ppm
36 mg/m³,
50 ppm
91 mg/m³
ethylene oxide
1 ppm
1.8 mg/m³
ND
ND
formaldehyde
2 ppm
2.5 mg/m³
1 ppm
1.2 mg/m³
1,4-dioxane
10 ppm
36 mg/m³
ND
ND
Engineering controls
Store in a well-ventilated place. Keep cool.
Personal protective equipment
Eye and face protection
Tightly sealed goggles.
Skin protection
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Body protection
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
9. PHYSICAL AND CHEMICAL PROPERTIES
General information
Appearance
Colourless liquid
Odour
Characteristic
pH
Not determined.
Vapour Pressure
Not determined
Density
Not determined
Boiling Point
Undetermined
Melting Point
Undetermined
Solubility
Fully miscible with water.
Specific Gravity of Density
Not determined.
Flash Point
>93.3 °C
Flammable (Explosive) Limits
Not determined.
Ignition Temperature
Not determined.
Formula
Not available.
10. STABILITY AND REACTIVITY
Reactivity
No further relevant information available.
Chemical stability
No decomposition if used according to specifications.
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No further relevant information available.
Incompatible materials
No further relevant information available.
11. TOXICOLOGICAL INFORMATION
Acute effects
The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version:
Harmful
Irritant
Harmful
Irritant
Eye contact
Irritating effect.
Skin contact
Irritant to skin and mucous membranes.
Ingestion
No further relevant information available.
Inhalation
Sensitisation possible through skin contact.
Toxicity and irritation
LD/LC50 values relevant for classification:
121-69-7 N,N-dimethylaniline
Oral LD50 1410 mg/kg (rat)
Dermal LD50 1770 mg/kg (rabbit)
75-07-0 acetaldehyde
Oral LD50 661 mg/kg (rat)
Inhalative LC50/4 h 37 mg/l (rat)
75-21-8 ethylene oxide
Oral LD50 72 mg/kg (rat)
Inhalative LC50/4 h 2671 mg/l (rat)
50-00-0 formaldehyde
Oral LD50 >200 mg/kg (rat)
123-91-1 1,4-dioxane
Oral LD50 5700 mg/kg (mouse)
Dermal LD50 7600 mg/kg (rabbit)
Inhalative LC50/4 h 46 mg/l (rat)
121-69-7 N,N-dimethylaniline
Oral LD50 1410 mg/kg (rat)
Dermal LD50 1770 mg/kg (rabbit)
75-07-0 acetaldehyde
Oral LD50 661 mg/kg (rat)
Inhalative LC50/4 h 37 mg/l (rat)
75-21-8 ethylene oxide
Oral LD50 72 mg/kg (rat)
Inhalative LC50/4 h 2671 mg/l (rat)
50-00-0 formaldehyde
Oral LD50 >200 mg/kg (rat)
123-91-1 1,4-dioxane
Oral LD50 5700 mg/kg (mouse)
Dermal LD50 7600 mg/kg (rabbit)
Inhalative LC50/4 h 46 mg/l (rat)
12. ECOLOGICAL INFORMATION
Ecotoxicity
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Water hazard class 3: extremely hazardous for water.
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
13. DISPOSAL CONSIDERATIONS
General information
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations.
Recommended cleansing agents: Water, if necessary together with cleansing agents.
Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations.
Recommended cleansing agents: Water, if necessary together with cleansing agents.
14. TRANSPORT INFORMATION
ADG label required
HAZCHEM
No further relevant information available.
UN Number
Not regulated.
Proper shipping name
Not regulated.
Transport hazard class
Not regulated
Packing group
Not regulated
Environmental hazard
Not applicable.
Special precautions for users
Not applicable.
Additional information
No information available.
15. REGULATORY INFORMATION
Poisons Schedule Number
ethylene oxide S7
formaldehyde S2, S6, S
formaldehyde S2, S6, S
Other Information
GHS07
Signal word Warning
Hazard-de
Signal word Warning
Hazard-de
16. OTHER INFORMATION
SDS preparation date
16 January 2023
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.